𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bicyclic aziridines as intermediates in the photolysis of polycyclic aromatic azides.

✍ Scribed by Jean Rigaudy; Christian Igier; Jacques Barcelo


Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
217 KB
Volume
20
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


According to the subsequent treatment, azepines 16, x, 19 or 1,2-dihydro derivatives 18 and 20 are obtained in the phctolysis in basic med%n of Bqnthracenic azides 7b and 7c<nd przide strong evidence for the intermedlate formation of bicyclic aziridinec -


πŸ“œ SIMILAR VOLUMES


Dimethylsulphide as a nitrene trap in th
✍ Martin J.P. Harger; Sally Westlake πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 132 KB

When PhRP(0)N3 (R = Ph or t-Du) is photolysed in dimethylsulphide substantial amounts (22 -3276) of PhRP(O)N:SMeZand PhRP(0)NHCH2SMe are produced and rearrangement is less important than in benzene. Phosphinic azides eliminate N2 on photol.ysis. The major pathway in methanol involves rearrangement t

Nickelatetrazoles as Intermediates in th
✍ DΓΆrte Kurz; Horst Hennig; Joachim Reinhold πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 German βš– 192 KB πŸ‘ 2 views

The primary photoreactions due to charge transfer excitation of d 8 transition metal complexes of [MP 2 (N 3 ) 2 ] constitution (P 2 : mono-or diphosphane ligands) are strongly influenced by the central ion. While [MP 2 (N 3 ) 2 ] complexes of both palladium(II) and platinum(II) yield primarily the