When PhRP(0)N3 (R = Ph or t-Du) is photolysed in dimethylsulphide substantial amounts (22 -3276) of PhRP(O)N:SMeZand PhRP(0)NHCH2SMe are produced and rearrangement is less important than in benzene. Phosphinic azides eliminate N2 on photol.ysis. The major pathway in methanol involves rearrangement t
Bicyclic aziridines as intermediates in the photolysis of polycyclic aromatic azides.
β Scribed by Jean Rigaudy; Christian Igier; Jacques Barcelo
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 217 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
According to the subsequent treatment, azepines 16, x, 19 or 1,2-dihydro derivatives 18 and 20 are obtained in the phctolysis in basic med%n of Bqnthracenic azides 7b and 7c<nd przide strong evidence for the intermedlate formation of bicyclic aziridinec -
π SIMILAR VOLUMES
The primary photoreactions due to charge transfer excitation of d 8 transition metal complexes of [MP 2 (N 3 ) 2 ] constitution (P 2 : mono-or diphosphane ligands) are strongly influenced by the central ion. While [MP 2 (N 3 ) 2 ] complexes of both palladium(II) and platinum(II) yield primarily the