๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Stereochemistry of grayanotoxin-II

โœ Scribed by Zenzaburo Kumazawa; Ryozo Iriye


Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
215 KB
Volume
11
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


๐Ÿ“œ SIMILAR VOLUMES


Stereochemistry of grayanotoxin
โœ Takeshi Matsumoto; Masahiko Watanabe ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 208 KB
The stereochemistry of the grayanotoxins
โœ H. Kakisawa; M. Yanai; T. Kozima; K. Nakanishi; H. Mishima ๐Ÿ“‚ Article ๐Ÿ“… 1962 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 219 KB
Stereoselective intramolecular aldol con
โœ Zenzaburo Kumazawa; Ryozo Iriye ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 200 KB

Grayanotoxin-II (1) and its dihydroderivatives can be oxidized with leadtetraacetate to corresponding secoketones which easily isomerize by alkaline treatment into respective tetrahydroxyketones (2). This paper deals with a circumstantial examination of the isomerization reaction towards both secok