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Reaction of grayanotoxin-II with mercuric acetate and the A/B ring junction of grayanotoxins

โœ Scribed by Junkichi Iwasa; Yukito Nakamura


Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
188 KB
Volume
10
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


The reaction of cyclic enol ethers with
โœ Ronald A. Wohl ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 194 KB

We would like to report a new general ring contraction reaction according to the following scheme (eq. l(a),R = ArSO,): The enol ether la derived from a cyclic ketone is reacted with a suitable aside leading via an intermediate unstable 6'-triazoline & to the ring-contracted imidate ester 3a.