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Stereochemical course of the modified polonovski reaction and mercuric acetate oxidation in the preparation of 2-substituted 1,2,3,4,6,7,12,12b-octahydroindolo[2, 3-a]quinolizines

✍ Scribed by Mauri Lounasmaa; Esko Karvinen

Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
543 KB
Volume
47
Category
Article
ISSN
0040-4020

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## Stereochemical control ' the preparation of 2substituted 1,2,3,4,6,7,12,12b-octahy~~oindoloI2,3-a,quinolizines possessing at will the C(12b)H-C(2)H cis or configuration trans was achieved by catalytic reduction ofthe 2,3-dehydro analoques, which were either unsubstituted on the indole nitrogen