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ChemInform Abstract: Rearrangement Reaction of 2-Methyltetrahydropyrans Having a C1′-Mesyloxy Group on the C2-Side Chain with Zinc Acetate: Ring Expansion and Ring Opening Reactions.

✍ Scribed by Yasuharu Sakamoto; Mina Koshizuka; Hiroyuki Koshino; Tadashi Nakata


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Rearrangement React
✍ Kazuo Nagasawa; Nobuyuki Hori; Hiroyuki Koshino; Tadashi Nakata 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB

Having a C1'-Mesyloxy Group on the C2-Side Chain with Zinc Acetate. -Depending on the stereostructure, tetrahydrofurans and tetrahydropyrans such as (I) and (VI) having a C1'-mesyloxy group on the C2-side chain undergo ring expansion or opening reactions to form a variety of products.