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Stereochemistry of free radical ring cleavage of cis-1,2,3-trimethylcyclopropane by bromine

โœ Scribed by Maynes, Gordon G.; Appliquist, Douglas E.


Book ID
126850692
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
798 KB
Volume
95
Category
Article
ISSN
0002-7863

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## Abstract 2โ€Methyleneโ€1,3โ€dioxepane 6 polymerized with a quantitative ring opening to form polyโ€ฯตโ€caprolactone via a free radical mechanism. On the other hand, 2โ€methyleneโ€1,3โ€dioxolane (ethylene ketene acetal) 4 and 2โ€methyleneโ€1,3โ€dioxane 5, under the same conditions, generated polymers with mi