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Stereochemistry of the electrophilic ring opening of cyclopropanes. 2. Reaction of cis- and trans-1,2,3-trimethylcyclopropane with deuterium(1+) ion

โœ Scribed by DePuy, C. H.; Fuenfschilling, P. C.; Andrist, A. H.; Olson, J. M.


Book ID
120074445
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
914 KB
Volume
99
Category
Article
ISSN
0002-7863

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## Abstract From the O~2~โ€dependence of the trapping rate of 1,1โ€difluoroโ€2,3โ€diphenylcyclopropane in supercritical CO~2~ in the temperature range 110โ€“180ยฐC and the rates of its geometrical isomerization and racemization of the __trans__โ€isomer, the energy profile for the geometrical isomerization