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Stereochemistry of addition of allylic Grignard reagents to 3-(hydroxymethyl)cyclopropenes

✍ Scribed by Richey, Herman G.; Bension, Rouvain M.

Book ID
125982130
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
1005 KB
Volume
45
Category
Article
ISSN
0022-3263

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Additions , promoted by the hydroxyl' function, of Grignard reagents to alkynols were reported in two recent communications. 2,3 The configurations (cis-trans) of the hydrolysis (H replacing \_-Mg) products obtained from the vinyl Grignard reagents that result from such additions are