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Addition of grignard reagents to the double bond of allylic alcohols

✍ Scribed by Marc Chérest; Hugh Felkin; Claude Frajerman; Claude Lion; Georges Roussi; Gérard Swierczewski

Publisher: Elsevier Science
Year: 1966
Tongue: French
Weight: 193 KB
Volume: 7
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)99699-6

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Reactive (ally1 and benzyl) Grignard reagents have been shorn to add to the double bond of allylic alcohols (I; Rv = H or Ar); the intermediates foraed in this reaction are probably the cyclic adducts II, vhich are themselves Grignard reagents and lead to a variety of products when treated vith suit

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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Additions , promoted by the hydroxyl' function, of Grignard reagents to alkynols were reported in two recent communications. 2,3 The configurations (cis-trans) of the hydrolysis (H replacing \_-Mg) products obtained from the vinyl Grignard reagents that result from such additions are