𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Additions of the allyl grignard reagent to allenols

✍ Scribed by Herman G. Richey Jr.; Stephen S. Szucs

Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
147 KB
Volume
12
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

We have observed additions of allylmagnesium chloride to allenols, reactions related to the additions to alkenols 1,2 and alkynols 2-4 that are promoted by the hydroxyl function. 5J6 In addition to providing interesting products, this investigation indicates that the products obtained from additions of Grignard reagents to alkynols would be accompanied by products resulting from additions to the allenols sometimes formed by isomerization of the alkynols.

πŸ“œ SIMILAR VOLUMES

The stereochemistry of additions of grig
The stereochemistry of additions of grignard reagents to alkynols
✍ Frederick W. Von Rein; Herman G. Richey Jr. πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 French βš– 229 KB

Additions , promoted by the hydroxyl' function, of Grignard reagents to alkynols were reported in two recent communications. 2,3 The configurations (cis-trans) of the hydrolysis (H replacing \_-Mg) products obtained from the vinyl Grignard reagents that result from such additions are