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Addition of organolithium reagents to the double bond of allylic alcohols

✍ Scribed by Hugh Felkin; Gérard Swierczewski; André Tambuté

Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
224 KB
Volume
10
Category
Article
ISSN
0040-4039

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✦ Synopsis

Reactive (ally1 and benzyl) Grignard reagents have been shorn to add to the double bond of allylic alcohols (I; Rv = H or Ar); the intermediates foraed in this reaction are probably the cyclic adducts II, vhich are themselves Grignard reagents and lead to a variety of products when treated vith suitable electrophiles (1).

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