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Stereochemical Studies on the Addition of Allylsilanes to Aldehydes. The SE' Component

✍ Scribed by Denmark, Scott E.; Almstead, Neil G.


Book ID
120533291
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
359 KB
Volume
59
Category
Article
ISSN
0022-3263

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The semiempirical study on the addition
✍ JarosΕ‚aw Lewkowski πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 138 KB

## Abstract The PM3 and AM1 semiempirical computations were performed in order to explain the stereochemistry of the addition of the chiral α‐methylbenzylammonium hypophosphite to an aldehyde, which is stereoselective to 100%. Both mechanisms: one considering the intermediate formation of α‐hydroxy