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ChemInform Abstract: Spectroscopic Studies on the TiCl4-Promoted Reaction of Allylsilanes with Aldehydes and α,β-Enones.

✍ Scribed by DENMARK, S. E.; ALMSTEAD, N. G.

Book ID
121373270
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
23
Category
Article
ISSN
0931-7597

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✍ M. MITANI; S. HUJITA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

The Reaction of Polyhalides with Allylsilanes Catalyzed by Copper(I) Chloride. -Allyltrimethylsilane (I) reacts with polyhalogen compounds (II) in the presence of copper species affording polyhalo compounds containing an allyl group. Other allylsilanes, e.g. (IV), (VI), and (IX), give various produ