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Stereochemical Studies on the Addition of Allylstannanes to Aldehydes. The SE' Component

✍ Scribed by Denmark, Scott E.; Hosoi, Shinzo

Book ID
126903867
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
295 KB
Volume
59
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

The stereochemistry of high pressure ald
The stereochemistry of high pressure aldehyde addition to allylstannanes
✍ Neil S. Isaacs; Raymond L. Marshall; David J. Young πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 French βš– 131 KB

The high pressure (9 kbar, 3oOC) mediated addition of benzaldehyde to allylstannane (1) occurs stereospecifically with syn approach of the electrophile. At 6OoC, the reaction is less selective, probably due to some isomerization of cis (1) to trun.s (1). At both temperatures good erythro diastexeose