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Stereochemical influence of the pentamethylcyclopentadienyl ligand on the isocyanide insertion reactions of the 1-sila-3-hafnacyclobutane complex,

✍ Scribed by Lioba Kloppenburg; Jeffrey L. Petersen


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
938 KB
Volume
14
Category
Article
ISSN
0277-5387

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## Abstract Application of new chiral ligands (__R__)‐(βˆ’)‐**12 a** and (__S__)‐(+)‐**12 c** (VALDY), derived from amino acids, to the title reaction, involving cinnamyl (linear) and isocinnamyl (branched) type substrates (**4** and **5** β†’ **6**), led to excellent regio‐ and enantioselectivities (>