Complex formation influence on reaction rate IV. Studies on the kinetic behavior of 3-carbomethoxy-1-methylpyridinium cation
โ Scribed by Dana Brooke; David E. Guttman
- Publisher
- John Wiley and Sons
- Year
- 1968
- Tongue
- English
- Weight
- 725 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0022-3549
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๐ SIMILAR VOLUMES
High-valent oxo-iron(IV) species are commonly proposed as the key intermediates in the catalytic mechanisms of iron enzymes. Water-soluble iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)porphyrin (Fe(III)TMPyP) has been used as a model of heme-enzyme to catalyse the hydrogen peroxide (H 2 O 2 ) o
Direct ab initio dynamic calculations are performed on the reactions of atomic hydrogen with GeD(n)(CH(3))(4-n) (n = 1-4) over the temperature range 200-2000 K at the PMP4SDTQ/6-311 +G(3df,2p)//MP2/6-31 +G(d) (for n = 2-4) and G2//MP2/6-31 +G(d) (for n = 1) levels. The corresponding k(H)/k(D) ratios