The mechanism of nucleophilic addition to η3-allylpalladium complexes: the influence of ligands on rates and regiochemistry
✍ Scribed by Björn Åkemark; Krister Zetterberg; Sverker Hansson; Bertil Krakenberger; Aldo Vitagliano
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 691 KB
- Volume
- 335
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The oxidative addition of the allylic acetate, CH 2 CH À CH 2 À OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h
## Abstract The chemical reduction of Pt(acac)~2~ by DIBALH in the presence of phosphanes, which is used to generate active Pt^0^ complexes in the Pt‐catalyzed silaboration of cyclohexadiene by 2‐(dimethylphenylsilyl)‐4,4,5,5‐tetramethyl‐1,3,2‐dioxaborolane (1) leading to the 1,4‐silaborated produc