𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Stereochemical Aspects in the Asymmetric Michael Addition of Chiral Imines to Substituted Electrophilic Alkenes

✍ Scribed by Cavé,, Christian; Desmaële, Didier; d'Angelo, Jean; Riche, Claude; Chiaroni, Angèle

Book ID
126053193
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
411 KB
Volume
61
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

2-Acetoxyacrylonitrile: use as electroph
2-Acetoxyacrylonitrile: use as electrophile equivalent to acetaldehyde in the asymmetric Michael reaction using chiral imines
✍ Laurent Keller; Cheikhou Camara; Antonio Pinheiro; Françoise Dumas; Jean d'Angel 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 81 KB

The asymmetric Michael addition reaction between a variety of chiral imines and 2-acetoxyacrylonitrile, an electrophile equivalent to acetaldehyde, was reported. The resulting adducts were obtained in fair yields and with de and ee ]95%.

High pressure activation in the asymmetr
High pressure activation in the asymmetric Michael addition of chiral imines to alkyl and aryl crotonates
✍ Cheikhou Camara; Delphine Joseph; Françoise Dumas; Jean d'Angelo; Angèle Chiaron 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 116 KB

High pressure-mediated Michael addition of chiral imines derived from 2-methylcyclopentanone, 2-methylcyclohexanone and optically active 1-phenylethylamine, to methyl and phenyl crotonates was investigated. The corresponding adducts were obtained in fair yields and with a high degree of regio-, dias