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Stepwise phosphorylation of vicinal diol and sterically hindered alcohol directed toward D-myo-inositol 2,4,5-trisphosphate

โœ Scribed by Yutaka Watanabe; Tomio Ogasawara; Naokazu Shiotani; Shoichiro Ozaki


Book ID
104227627
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
239 KB
Volume
28
Category
Article
ISSN
0040-4039

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Regioselective phosphorylation of vicina
โœ Fushe Han; Minoru Hayashi; Yutaka Watanabe ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 304 KB

The reactivity of 3 and 4-OH in 3,4-diol myo-inositol derivatives were observed through the phosphorylation, acylation and silylation. The results indicated that 3-OH is much more reactive than 4-OH, giving regiospecifically 3-mono-functionalized products. This investigation provided a concise metho