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Stepwise Mechanisms in the Oxy-Cope Rearrangement

โœ Scribed by Berson, Jerome A.; Jones, Maitland.


Book ID
126335801
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
242 KB
Volume
86
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


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## An aromatic oxy-Cope rearrangement can be achieved under anionic conditions (KH f HMPAl in Zow yield with a nuphthalene ring but not a phenyt. We have recently measured the activation parameters for an aromatic Cope rearrangement,l and these sug,oest that rearrangement of 4-phenyl-1-butene wou

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The anionic oxy-Cope rearrangement has emerged as a highly useful tool for organic synthesis. [1, 2] Various 1,5-dien-3ols readily undergo this electronic reorganization, and the usually easy preparation of the precursors contributes to the popularity of this reaction. However, a limitation of this