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Electronic aspect of face selection in the oxy-Cope rearrangement

โœ Scribed by Lin, Man Hua; Le Noble, W. J.


Book ID
126821736
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
224 KB
Volume
54
Category
Article
ISSN
0022-3263

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The iron nicarbonyl complexes of I-(2-adamantylidene)-2-methylenecyclohexane and of the 5fluoroadarnantylidene analog have been prepared. Both the m and anti isomers were obtained in the latter case; the major product has the E configuration as established by means of X-ray diffraction. The reaction