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Multiplicity of Mechanisms in the Cope Rearrangement

โœ Scribed by Hammond, George S.; DeBoer, Charles D.


Book ID
126837150
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
433 KB
Volume
86
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


Mechanism of the Cope rearrangement
โœ Dewar, Michael J. S.; Jie, Caoxian ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 892 KB
The mechanism of the Cope rearrangement
โœ Gajewski, Joseph J.; Conrad, Neal D. ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 254 KB
Evidence for alternative mechanisms in t
โœ Steven M. Allin; Martin A.C. Button ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 95 KB

The formal amino-Cope rearrangement of a 3-amino-l,5-diene substrate does not proceed solely by a concerted [3,3]-sigmatropic rearrangement mechanism.

The three mechanisms for cope rearrangem
โœ Donald C. Wigfield; Kevser Taymaz ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 205 KB

There is evidence that Cope Rearrangements may occur by as many as four distinct mechanisms, of which only one is the usual concerted mechanism (1). In 1972, Goldstein and Benzon reported the discovery of a second degenerate rearrangement of 1,5-hexadiene, occurring only at high temperature (250-300