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Mechanism of the Cope rearrangement

โœ Scribed by Dewar, Michael J. S.; Jie, Caoxian


Book ID
115443403
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
892 KB
Volume
109
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


The three mechanisms for cope rearrangem
โœ Donald C. Wigfield; Kevser Taymaz ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 205 KB

There is evidence that Cope Rearrangements may occur by as many as four distinct mechanisms, of which only one is the usual concerted mechanism (1). In 1972, Goldstein and Benzon reported the discovery of a second degenerate rearrangement of 1,5-hexadiene, occurring only at high temperature (250-300

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The 3-aza-Cope rearrangements of 3-azoniahexa-1,5-diene (1), 3-azoniahex-1-ene-5-yne (3), and 3-azahex-1-ene-5-yne (5) were investigated up to the coupled-cluster level, CCSD(T), by using a valence triple-zeta basis set. Activation barriers and geometrical parameters of the transition states are pro

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