## Abstract Syntheses of palmitic acidโd~2~ and stearic acidโd~6~ are described, the latter route also having the capability of producing methyl oleate and elaidateโ13,13,14,14โd~4~ from the same synthetic sequence. Overall yields are in the range of 40 to 60%. These syntheses use __tris__ (triphen
Stearic acid or palmitic acid as a substitute for trans fatty acids?
โ Scribed by John C. Stanley
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2009
- Tongue
- English
- Weight
- 341 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0956-666X
No coin nor oath required. For personal study only.
โฆ Synopsis
Abstract
The evidence for unfavourable effects of trans fatty acids on risk of developing coronary heart disease is overwhelming. The food industry must now search for substitutes for trans fatty acids with acceptable nutritional properties which at the same time retain the functionality of fats for baking and margarine manufacture. Comparisons of fats rich in stearic acid with fats rich in mixtures of palmitic, myristic and lauric acids show that fasting total and LDLโcholesterol levels, postprandial lipaemia and factor VII activation are lower in response to stearic rich fats. All of these effects of stearic acid would be expected to lower the risk of developing coronary heart disease by comparison with palmitic acid. While fasting HDLโcholesterol levels are higher in response to the saturated fatty acid mixture than in response to stearic acid this is probably due to the lauric acid content of the mixture rather than its palmitic acid content. To date there is no evidence that randomization of stearic acid or palmitic acid caused by interesterification has any effect on risk factors for coronary heart disease although more research is needed. It can be concluded that stearic acid is a better substitute for trans fatty acids than palmitic acid in fats for baking and margarine manufacture.
๐ SIMILAR VOLUMES
In previous studies from this laboratory, a mediated transport system for long chain fatty acids was observed in rat renal basolateral membrane vesicles. Transport was measured in the absence of albumin and indicated the presence of a Na+ independent anion exchange mechanism. The present experiments
Epoxidized linseed oil-free fatty acids were reacted with aniline and three isomers of toluidine, anisidine, and chloroaniline in such a manner that the carboxylic groups remained free. The prepared adducts were evaluated as antioxidants and antirads for styrene butadiene rubber (SBR) vulcanizates.