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States of hydrogen in crystalline silicon

✍ Scribed by M. Stutzmann; W. Beyer; L. Tapfer; C.P. Herrero


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
306 KB
Volume
170
Category
Article
ISSN
0921-4526

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✦ Synopsis


Thc thermal transformation ol deuterium it] p-type crvslallinc silicon is sludicd wilt] a '~aricty ol experimental techniques. It is found lhal D-atolns initially mippcd at acceptor sites can hc transferred b~ low temperature annealing to a different state lcnlati~,c]\ ascribed to intcrstilia[ l). molecules, l)itfusion ol I) out of tt3c passixalcd sample only, occurs al temperatures significantly higher lhan this transformation temperature. This fact allows us to producc Si samplcs x,,ith cxtrelllelv high deuterium concentrations (several at<~ ) by a suitable passi\ation annealing >,Cqtlcncc. \Vilh increasing D concentration, a number of characleristic Si D dcfccl complexes have been observed by vibralional spΒ’ctroscop).


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Hydrogen is commonly introduced into silicon solar cells to reduce the deleterious effects of defects and to increase cell efficiency. A process that is widely used by industry to introduce hydrogen is by the post-deposition annealing of a hydrogen-rich SiN x layer that is used as an anti-reflection