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Stable nitrogen pyramids III. N-aminoaziridines

โœ Scribed by Stanley J. Brois

Book ID
104212434
Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
125 KB
Volume
9
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Recently, we discovered (1,2) that N-haloaziridinea (3) exist as stable pyramidal

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โœ Tomohiko Ohwada; Iwao Okamoto; Koichi Shudo; Kentaro Yamaguchi ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 272 KB

The pyramidalization of the nitrogen in sulfonamides of 7-azabicyclo[2.2.1 ]heptane is enhanced in the solid state as compared with the corresponding monocyclic sulfonamides of pyrrolidine and 3-pyrroline. We postulate a general structural motif of pyramidal nitrogen in sulfonamides.