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Intrinsic pyramidal nitrogen of N-sulfonylamides

โœ Scribed by Tomohiko Ohwada; Iwao Okamoto; Koichi Shudo; Kentaro Yamaguchi

Book ID
104260021
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
272 KB
Volume
39
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The pyramidalization of the nitrogen in sulfonamides of 7-azabicyclo[2.2.1 ]heptane is enhanced in the solid state as compared with the corresponding monocyclic sulfonamides of pyrrolidine and 3-pyrroline. We postulate a general structural motif of pyramidal nitrogen in sulfonamides.

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