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Pyramidal amide nitrogen in N-acyldiaziridines and N-acyloxaziranes

โœ Scribed by R. G. Kostyanovskii; K. S. Zakharov; M. Zaripova; V. F. Rudchenko

Book ID
112436876
Publisher
Springer
Year
1975
Tongue
English
Weight
709 KB
Volume
24
Category
Article
ISSN
1573-9171

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Asymmetrical nonbridgehead nitrogen. VI
Asymmetrical nonbridgehead nitrogen. VI nitrogen pyramide in amides: N-acyldiaziridines and N-acyloxaziridines
โœ R.G. Kostyanovsky; K.S. Zakharov; M. Zaripova; V.F. Rudtchenko ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 255 KB

This work provides a proof of pyramidal configuration of nitrogen in N-acyldiaziridines I-IX and N-acyloxaziridine X (see Table 1)(2). In respect to the NMR time scale the inversion of this configuration is fairly slow. The data presented here are in agreement with an earlier observation (3) that th