Stable 1,2,4-triazolo[1,5-a]-pyrimidinium salts
✍ Scribed by N. N. Kolos; V. D. Orlov; B. V. Paponov; O. V. Shishkin; S. V. Baumer; N. A. Kvashnitskaya
- Publisher
- Springer US
- Year
- 1999
- Tongue
- English
- Weight
- 507 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0009-3122
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The chemical reactivity of the [1,2,3]triazolo[1,5-a]-and [1,5-c]-pyrimidinium salts towards morpholine, water and sodium methoxide have been studied. Among others, new 1-aza and 2-azabutadienes substituted by a [1,2,3]-triazole ring were obtained in the course of the opening of the positively charg
With sodium borohydride in tetrahydrofuran/ethanol (5 : 1). the product ( I ) gives a 75 yield of a compound, m.p. 233 "C, that is identical with the recently prepared 2-(diphenylmethyl)imidaz0le[~1. When product ( I ) is boiled for 2 h in tetrahydrofuran/water (2: I ) it affords 2-(hydroxy-dipheny