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Chemical reactivity of [1,2,3]triazolo[1,5-a]- and [1,5-c]-pyrimidinium salts

✍ Scribed by Sándor Bátori; Eszter Gács-Baitz; Sándor Bokotey; András Messmer


Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
169 KB
Volume
59
Category
Article
ISSN
0040-4020

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✦ Synopsis


The chemical reactivity of the [1,2,3]triazolo[1,5-a]-and [1,5-c]-pyrimidinium salts towards morpholine, water and sodium methoxide have been studied. Among others, new 1-aza and 2-azabutadienes substituted by a [1,2,3]-triazole ring were obtained in the course of the opening of the positively charged pyrimidine ring.


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Synthesis of 1,2,3-Triazolo[1,5-a]quinox
✍ Dr. A. Messmer; Dipl.-Chem. O. Szimán 📂 Article 📅 1965 🏛 John Wiley and Sons 🌐 English ⚖ 118 KB 👁 1 views

With sodium borohydride in tetrahydrofuran/ethanol (5 : 1). the product ( I ) gives a 75 yield of a compound, m.p. 233 "C, that is identical with the recently prepared 2-(diphenylmethyl)imidaz0le[~1. When product ( I ) is boiled for 2 h in tetrahydrofuran/water (2: I ) it affords 2-(hydroxy-dipheny