## Abstract For Abstract see ChemInform Abstract in Full Text.
Chemical reactivity of [1,2,3]triazolo[1,5-a]- and [1,5-c]-pyrimidinium salts
✍ Scribed by Sándor Bátori; Eszter Gács-Baitz; Sándor Bokotey; András Messmer
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 169 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0040-4020
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✦ Synopsis
The chemical reactivity of the [1,2,3]triazolo[1,5-a]-and [1,5-c]-pyrimidinium salts towards morpholine, water and sodium methoxide have been studied. Among others, new 1-aza and 2-azabutadienes substituted by a [1,2,3]-triazole ring were obtained in the course of the opening of the positively charged pyrimidine ring.
📜 SIMILAR VOLUMES
With sodium borohydride in tetrahydrofuran/ethanol (5 : 1). the product ( I ) gives a 75 yield of a compound, m.p. 233 "C, that is identical with the recently prepared 2-(diphenylmethyl)imidaz0le[~1. When product ( I ) is boiled for 2 h in tetrahydrofuran/water (2: I ) it affords 2-(hydroxy-dipheny