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Synthesis of 1,2,3-Triazolo[1,5-a]quinoxalinium and 1,2,3-Triazolo[5,1-c]-benzo-1,2,4-triazinium Salts

✍ Scribed by Dr. A. Messmer; Dipl.-Chem. O. Szimán


Publisher
John Wiley and Sons
Year
1965
Tongue
English
Weight
118 KB
Volume
4
Category
Article
ISSN
0044-8249

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✦ Synopsis


With sodium borohydride in tetrahydrofuran/ethanol (5 : 1).

the product ( I ) gives a 75 yield of a compound, m.p. 233 "C, that is identical with the recently prepared 2-(diphenylmethyl)imidaz0le[~1. When product ( I ) is boiled for 2 h in tetrahydrofuran/water (2: I ) it affords 2-(hydroxy-dipheny1methyl)imidazole in 72 % yield. Addition of the calculated amount of ethereal hydrogen chloride to a solution of product ( I ) in tetrahydrofuran regenerates the starting material (2) almost quantitatively.


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