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Stabilization of α-Helices by Dipole−Dipole Interactions within α-Helices

✍ Scribed by Park, Changmoon; Goddard, William A.

Book ID
125996152
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
244 KB
Volume
104
Category
Article
ISSN
0022-3654

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The electrostatic interactions between a-helix dipoles in the crystals of an uncharged helical undecapeptide have been studied in detail. The electrostatic interaction energy between one helix dipole and its 26 nearest neighbors is approximately -23 kcal mol-'. A very similar result is obtained when