Optrcal spectrophotometry has been used to mvesugate the product of electron additron to CCl, m solvents of dtfferent nature It IS shown that In "ngd" matnces (9 Z-10 l9 P) Ccl; ra&cal amens are formed, whereas u1 a "soft" envIronmen (9 c 1019 P) Ccl; undergoes &ssoclalton mlo Ccl, radxals and Cl-Io
Stabilization and photochemical reactions of thiyl radicals in glassy matrices at 77 k
โ Scribed by Yu.V. Razskazovsky; M.Ya. Mel'nikov
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 782 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0047-2670
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๐ SIMILAR VOLUMES
Absorption and fluorescence spectra of ghssy solutions of some trans-stilbme-like molecules were found to differ remarkably provided trans-dhrylerhylenes were obtained photochemically at 77 K in siru. The phenomenon has been rationalized ns being due 10 the production of non-equilibrium concentratio
The intensity ratio of two Raman bands was measured at various resonant excitation wavelengths for the radical cation of naphthalene. By comparing the observed intensity ratio with calculation, the partitioning of the electronic spectral width into homogeneous and inhomogeneous components was perfor