Electron spin resonance spectra of the lowest excited triplet state of 9,10-anthnquinone are detected in a gass matrix at 77 K using a time-resolved technique. Computer simulation trials of the randomly oriented spin-polarized ESR spectra lead to the postuiare of a wide d~t~b~tion of the zero-field
✦ LIBER ✦
Time-resolved ESR detection of benzophenone nπ* triplet state in glassy matrices at 77 K
✍ Scribed by Hisao Murai; Takashi Imamura; Kunichi Obi
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 286 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0009-2614
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Benzophenone forms a weak complex with diethylaniline in the ground state at 77 K. Laser photolysis studies carried out for a neat diethylaniline solution of benzophenone at 77 K reveal that the excited triplet state of the weak complex has a strong charge-transfer structure and exhibits a transient