✦ LIBER ✦

Stabilization of CCl4− radical anions in glassy matrices at low temperatures

✍ Scribed by E.Kh. Brickenstein; R.F. Khairutdinov

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 319 KB
Volume: 115
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)80674-6

No coin nor oath required. For personal study only.

✦ Synopsis

Optrcal spectrophotometry has been used to mvesugate the product of electron additron to CCl, m solvents of dtfferent nature It IS shown that In "ngd" matnces (9 Z-10 l9 P) Ccl; ra&cal amens are formed, whereas u1 a "soft" envIronmen (9 c 1019 P) Ccl; undergoes &ssoclalton mlo Ccl, radxals and Cl-Ions. The possible reasons for slabllwauon of the Ccl, rackal amens m sohd me&a are dlscussed

📜 SIMILAR VOLUMES

Stabilization and photochemical reaction

Stabilization and photochemical reactions of thiyl radicals in glassy matrices at 77 k

✍ Yu.V. Razskazovsky; M.Ya. Mel'nikov 📂 Article 📅 1984 🏛 Elsevier Science ⚖ 782 KB

Vacuum-ultraviolet absorption spectra of

Vacuum-ultraviolet absorption spectra of mercury atoms trapped in inert-gas matrices at low temperatures

✍ W.W. Duley 📂 Article 📅 1965 🏛 Elsevier Science ⚖ 144 KB

The radiolysis of alcohols at low temper

The radiolysis of alcohols at low temperatures—II. The precursors of hydrogen in glassy alcohols up to n-hexanol including allyl alcohol. The hydrogen formation in irradiated glassy alcohols at 77 K

✍ J. Teplý; I. Janovský; A. Habersbergerová; L. Karasová 📂 Article 📅 1970 🏛 Elsevier Science ⚖ 751 KB

Studies on the fluorescence decay times

Studies on the fluorescence decay times of anthracene and perylene excimers in rigid matrices at low temperatures in relation to the structures of excimers

✍ N. Mataga; Y. Torishashi; Y. Ota 📂 Article 📅 1967 🏛 Elsevier Science 🌐 English ⚖ 289 KB

The fluorescence decay times of excimers of anthracene, perylene, pyrene aud 1-methylnapbthalene have been studied in a rigid cyclohexane matrix of low temperatures. From the observed long decay times of the excimer fluorescence, it has been concluded that the excimer fluorescence is due to the ele

Relaxation studies of carbonyl rhenium c

Relaxation studies of carbonyl rhenium clusters. Part 2—relaxation mechanisms and estimation of the 13C chemical shielding anisotropy in the [Re3(μ-H)4(CO)10]− anion at low temperature

✍ Tiziana Beringhelli; Giuseppe D'Alfonso; Henriette Molinari 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 483 KB

## Application of the non-selective inversion recovery technique to 13C spectra of moderately enriched [Re,(p-H),(CO),]-indicates that relaxation times, at low temperatures, are strongly field dependent and decrease with increasing field strength. Measurements performed at 183K and at 20.15, 50.31