## Abstract The stability of some Schiff‐bases formed between PLP and different amino acids has been investigated in a wide range of pH. The kinetic constants of formation of these compounds and their hydrolysis rate constants have been determined. Results show that the α‐position of the carboxyl g
Stability of Schiff bases of amino acids and pyridoxal-5′-phosphate
✍ Scribed by M. A. Vázquez; F. Muñoz; J. Donoso; F. García Blanco
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 727 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0939-4451
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We studied the formation and hydrolysis of the Schiff base of pyridoxal-5'-phosphate (PLP) and n-dodecylamine (DOD) by kinetic methods and found the formation rate constants to be much larger than those reported for related systems. This can be ascribed to the occurrence of local concentration of ch
We determined the apparent equilibrium constant of formation, KpH, of the Schijf bases of pyridoxal 5'-phosphate (PLP) and poly-and copolymers containing L-lysine, as a function of pH at 25" and a constant ionic strength of 0 . 1 ~. The KPH values obtained at acidic and neutral pH were larger that t