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Sr2BN2I: A Strontium Iodide Compound with Isolated BN3−2Units

✍ Scribed by Franziska E. Rohrer; Reinhard Nesper

Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
229 KB
Volume
142
Category
Article
ISSN
0022-4596

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✦ Synopsis

The compound Sr 2 BN 2 I was synthesized from a mixture of the binary components Sr 3 N 2 , SrI 2 , and BN in sealed steel ampoules at 1150 K. The structure was refined from single crystal data. Sr 2 BN 2 I crystallizes with the monoclinic symmetry P2 /m (No. 11) with a ‫؍‬ 10.284(7) A s , b ‫؍‬ 4.224(3) A s , c ‫؍‬ 13.246(9) A s , ‫؍‬ 90.87(6)°, Z ‫؍‬ 4, and V ‫؍‬ 575.3(7) A s 3 . The structure is built from isolated BN 3؊ 2 anions and quite distorted Sr 6 I octahedra.

📜 SIMILAR VOLUMES

Ba8(BN2)5F: A Barium Fluoride Compound w
Ba8(BN2)5F: A Barium Fluoride Compound with Isolated BN3−2Units
✍ Franziska E Rohrer; Reinhard Nesper 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 267 KB

The compound Ba 8 (BN 2 ) 5 F was synthesized from a mixture of the binary components Ba 3 N 2 , BaF 2 , and BN in sealed steel ampoules at 1273 K. The structure was refined from single crystal data. Ba 8 (BN 2 ) 5 F crystallizes with the triclinic symmetry P1 (No. 2) with a ‫؍‬ 4.204(3) A s , b ‫؍‬

ChemInform Abstract: Ternary Nitridobora
ChemInform Abstract: Ternary Nitridoborates. Part 1. LiMg(BN2) (I) and Ba4(BN2)2O (II) - Compounds with the Anion (N-B-N)3-: Syntheses, Crystal Structures, and Vibrational Spectra.
✍ M. SOMER; U. HERTERICH; J. CURDA; W. CARRILLO-CABRERA; K. PETERS; H. G. VON SCHN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

Nitridoborates. Part 1. LiMg(BN2) (I) and Ba4(BN2)2O (II) -Compounds with the Anion (N-B-N)3-: Syntheses, Crystal Structures, and Vibrational Spectra. -The title compounds are prepared by solid state reaction of stoichiometric mixtures of Li3N, Mg3N2, and BN for (I) and BaO, Ba3N2, and BN for (II)