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Spontaneous asymmetric crystallization of a quartz-type framework from achiral precursors

✍ Scribed by Zheng, Wenxu; Wei, Yongqin; Xiao, Xueying; Wu, Kechen


Book ID
115481835
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
990 KB
Volume
41
Category
Article
ISSN
1477-9226

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ChemInform Abstract: A Novel Asymmetric
✍ Feng Zhou; Michael R. Detty; Rene J. Lachicotte πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 2 views

A Novel Asymmetric Synthesis of 2-Azetidinones from Achiral Precursors. -Cyclocondensation of chloride (I) with p-methoxybenzylamine in the presence of stoichiometric amounts of a chiral salen-copper(II) is investigated. The desired azetidinone (III) is obtained with considerable enantioselectivity