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Splitless injection and the solvent effect

✍ Scribed by Grob, K. ;Grob, K.

Book ID
102892755
Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
700 KB
Volume
1
Category
Article
ISSN
0935-6304

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✦ Synopsis

Abstract

Splitless injection is based on the solvent effect as a mechanism condensing large vapour clouds down to infinitely shortened bands. The effect is controlled by the parameters column temperature, volatility and amount of solvent, and rate of injection. By properly selecting the variables the effect can easily be optimized for any combination of sample and column. It is the purpose of this paper to provide the mechanistic understanding as required for this optimization, as well as some rules for the experimental realization. Potentialities and limitations of splitless injection are discussed, and the role of the solvent effect in on‐column injection is emphasized.

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