𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Spiro[4.5]decanes by photoannelation. Total synthesis of (−)-acorenone

✍ Scribed by S.W. Baldwin; J.E. Fredericks

Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
276 KB
Volume
23
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

ChemInform Abstract: Synthesis and Chara
ChemInform Abstract: Synthesis and Characterization of Optically Active Spiro[4.5]decanes.
✍ Sara Rafel; Gemma Cabarrocas; Montserrat Ventura; Teo Parella 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

Synthesis and Characterization of Optically Active Spiro[4.5]decanes. -Three different dienes (I), substituted with a chiral auxiliary at the 1-position, and dienophiles (II) or (VII) undergo a Diels-Alder cycloaddition with quite good diastereofacial selectivity. The Si-exo and Re-endo diastereomer

A new strategy for the synthesis of spir
A new strategy for the synthesis of spiro[4,5]decanes: A formal total synthesis of acorone
✍ P.John Biju; G.S.R.Subba Rao 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 145 KB

A new strategy for the construction of spiro [4,5]decanes is described and involves a bridgehead substitution of a methoxyl group in 6 by a methyl group, followed by an oxidative cleavage resulting in a stereogenic spirocentre which culminated in the formal synthesis of acorone.