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ChemInform Abstract: Total Synthesis of (.+-.)-Gleenol and (.+-.)-Axenol via a Functionalized Spiro[4.5]decane.

โœ Scribed by Atsuo Nakazaki; Tomohiro Era; Susumu Kobayashi

Publisher
John Wiley and Sons
Year
2008
Weight
43 KB
Volume
39
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis and Chara
ChemInform Abstract: Synthesis and Characterization of Optically Active Spiro[4.5]decanes.
โœ Sara Rafel; Gemma Cabarrocas; Montserrat Ventura; Teo Parella ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 1 views

Synthesis and Characterization of Optically Active Spiro[4.5]decanes. -Three different dienes (I), substituted with a chiral auxiliary at the 1-position, and dienophiles (II) or (VII) undergo a Diels-Alder cycloaddition with quite good diastereofacial selectivity. The Si-exo and Re-endo diastereomer