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Spin trapping reactions with nitric oxides IV. Reactions with olefins

✍ Scribed by Antal Rockenbauer; Miklós Győr; Ferenc Tüdős


Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
214 KB
Volume
27
Category
Article
ISSN
0040-4039

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Spin trapping reactions with nitric oxid
✍ A. Rockenbauer; M. Győr; F. Tüdős 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 209 KB

Radical trapping by nitric oxide in the presence of oxygen has been studied by EsR spectroscopy. The oxygen was found to react much faster with alkyl radicals than nitric oxide, it suppresses formation of dialkyl nitroxides and initiatescreation of acyl nitroxides through reactions between peroxy ra

Spin trapping reactions with nitric oxid
✍ Miklós Győr; Antal Rockenbauer; Ferenc Tüdős 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 221 KB

Formation of macromolecular nitroxides (i.e., spin labeled polymer chains) has been detected by Electron Spin Resonance spectroscopy in the reaction of nitric oxide gas with several unsaturated polymers /synthetic polyisoprene, polybutadiene, poly(isoprene-co-isobutylene), poly(butadiene-co-styrene)

Spin trapping reactions with nitric oxid
✍ A. Rockenbauer; M. Győr; F. Tüdős 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 227 KB

Subsequent trapping of photochemically generated alkyl and alkoxy radicals by nitric oxide yields alkoxyalkylnitroxide radicals. New types of nitrogen centered radicals have been detected and tentatively explained by reactions of nitrogen oxides N20, NO, N02, N203, N204 with alkyl and peroxide radic

Reaction of amides with nitric oxide (NO
✍ Takashi Itoh; Kazuhiro Nagata; Yûji Matsuya; Michiko Miyazaki; Akio Ohsawa 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 215 KB

Amides were allowed to react with nitric oxide in aprotic and non-ethereal solvents to give the corresponding N-nittoso derivatives. The reaction was accelerated by addition of oxygen. The solvent effect revealed that the reaction did not proceed in the presence of protic media.