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Spin trapping reactions with nitric oxides. V. Reactions with unsaturated macromolecular chains - a new spin labeling method

✍ Scribed by Miklós Győr; Antal Rockenbauer; Ferenc Tüdős

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
221 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis

Formation of macromolecular nitroxides (i.e., spin labeled polymer chains) has been detected by Electron Spin Resonance spectroscopy in the reaction of nitric oxide gas with several unsaturated polymers /synthetic polyisoprene, polybutadiene, poly(isoprene-co-isobutylene), poly(butadiene-co-styrene)/ dissolved in aromatic hydrocarbons. Spectroscopic evidences of gel formation, precipitation, and of solvent effect have been given.

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