Spectrum shape studies of the β-transitions 34mCl(3+ → 2+) 34S and 34Cl(0+ → 0+) 34S
✍ Scribed by Th. Krüger; H. Appel; W.-G. Thies; H. Behrens
- Book ID
- 113346967
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 259 KB
- Volume
- 121
- Category
- Article
- ISSN
- 0370-2693
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High-resolution (0.0015 cm À1 ) infrared spectroscopy has been used to study the 34 S 16 O 3 IR-active hot bands originating from the m 2 and m 4 bending mode levels and terminating in the states 2m 2 ðl ¼ 0Þ, m 2 þ m 4 ðl ¼ AE1Þ, and 2m 4 ðl ¼ 0; AE2Þ. The upper states are strongly coupled via Ferm
The infrared spectrum of the m 2 ; m 4 bending mode region of 34 S-substituted sulfur trioxide, 34 S 16 O 3 , has been recorded at a resolution of 0:0025 cm À1 . The m 2 and m 4 levels are coupled by a Coriolis interaction, yielding significant spectral shifts that have been successfully analyzed to