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The influence of lanthanide ionic radii on the formation and stability of the complexes: Synthesis, chemical properties and characterization of [(β-SiW9O34)2(H2OM)3CO3]13− M = Eu3+ and Gd3+

✍ Scribed by Roushan Khoshnavazi; Leila Bahrami; Sahar Gholamyan


Book ID
108213368
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
653 KB
Volume
990
Category
Article
ISSN
0022-2860

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✍ Ding-Xian Jia; Jie Deng; Qian-Xin Zhao; Yong Zhang 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 309 KB

Two new lanthanide thioantimonates, [Pr(en) 3 (H 2 O)(l 2 -SbS 4 )] and [Gd(en) 4 ]SbS 4 AE0.5en (en = ethylenediamine), were synthesized using the solvothermal method by reacting LnCl 3 , Sb and S in en at 160 °C. The crystal structure of 1 consists of a one-dimensional [Pr(en) 3 (H 2 O)(l 2 -SbS 4