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Synthesis and crystal structure of a hexanuclear rhenium cluster complex Cs3K[Re6(μ3-S)6 (μ3-Te0.66S0.34)2(CN)6]. Cationic control over orientation of the cluster anion

✍ Scribed by Yuri V. Mironov; Alexander V. Virovets; Vladimir E. Fedorov; Nina V. Podberezskaya; Oleg V. Shishkin; Yuri T. Struchkov


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
189 KB
Volume
14
Category
Article
ISSN
0277-5387

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✍ Yue-Qing Zheng; Karl Peters; Yuri Grin; Hans Georg von Schnering 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 254 KB 👁 1 views

K 2 W 6 Br 14 (I), Rb 2 W 6 Br 14 (II), and Cs 2 W 6 Br 14 (III) were formed by reactions of W 6 Br 12 with the corresponding alkali metal bromides in evacuated silica tubes with a temperature gradient of 925 K/915 K. (I) crystallizes in the cubic space group Pn3 (no. 201), a = 13.808 A Ê , Z = 4, c