Femtosecond transient absorption studies of charge-transfer complexes of 12 with hexamethylbenzene have been performed in a series of noncomplexing solvents. Anisotropy measurements of the bleach of the charge-transfer absorption band indicate that the geometry and electronic structure of the comple
Spectroscopic Study of the Effect of High Pressures on Organic Charge-Transfer Complexes in Solution
β Scribed by Gott, J. Robert; Maisch, William G.
- Book ID
- 119966367
- Publisher
- American Institute of Physics
- Year
- 1963
- Tongue
- English
- Weight
- 796 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0021-9606
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π SIMILAR VOLUMES
High-pressure infrared spectra of tetrathiafulvalene-chloranil ('ITF-CA) indicate that the neutral-to-ionic transition occurs abruptly at a pressure of 7.8kO.5 kbar. High-pressure visible and infrared spectra on perylene-tetracyanoethylene (perylene-TCNE) showed no changes which could be attributed
Ahstraet-Crystals of organic charge-transfer complexes were grown by electrochemical oxidation of bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) in the presence of trihalide anions in various solvents. In order to 8nd the optimal conditions to grow the large, good quality crystals necessary for t
## Abstract Thermodynamic and spectroscopic properties of the chargeβtransfer complex acenaphteneβtetrachlorophtalic anhydride were studied in different solvents. The corresponding thermodynamic and spectroscopic parameters were corrected for solvent competition. Only in this case were correlations