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Spectroscopic properties and mode of bonding of thiocyanate ligand in some Ru(III) complexes

โœ Scribed by Stanislaw Wajda; Krystyna Rachlewicz

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
543 KB
Volume
31
Category
Article
ISSN
0020-1693

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โœฆ Synopsis

Zhe existence of a mixed mode of bonding of the thiocyanate groups by sulfur and by nitrogen in hexathiocyanato and tetrathiocyanato bisammine Ru(III) complexes has been confirmed recently. This conception has been accepted on the basis of both the analyses of vibrational spectra and a study of isotopic exchange kinetics and Mtissbauer spectrum The suggestions pertaining to the structure of complexes under study which have been discussed above find their confirmation in the results of studies of far infrared spectra, in the integrated intensity value of the vc__N band as Wd as in an andySiS of electronic and circular dichroism spectra

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