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K-absorption spectra and the nature of metal-ligand bond in some cobalt complexes

✍ Scribed by V. Krishna; J. Prasad; H.L. Nigam

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
367 KB
Volume
20
Category
Article
ISSN
0020-1693

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✦ Synopsis

Shifts and widths of the K-absorption edge of cobalt in a specifically chosen variety 'and number of complexes involving donor atoms like nitrogen, oxygen and sulphur have been measured using a bent crystal spectrograph. The expected change in ionic/ covalent character of the metal-ligand bo&l in these complexes on the basis of PaulingS electronegativities and also observed from the optical spectra (where known) appears to be reflected in their X-ray edgeshifts and widths.

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