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Spectroscopic Investigation of the System TeCl4/[NEt4]PF6 in Solution and the Crystal Structure of [NEt4]2[Te2Cl10].

✍ Scribed by Holger Fleischer; Dieter Schollmeyer


Publisher
John Wiley and Sons
Year
2005
Weight
12 KB
Volume
36
Category
Article
ISSN
0931-7597

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An ampule reaction between Mo and PCl 5 at 200 °C yielded (PCl 4 ) 2 [Mo 2 Cl 10 ], the first ternary compound in Mo±P±Cl system. Single crystal X-ray diffraction gave a triclinic unit cell: a = 6.870(1), b = 8.892(2), c = 9.423(2) A Ê , α = 100.24(2), b = 95.55(2), c = 96.12(2)°(V = 559.3(2) A Ê 3